B, degradable and reusable products can reduce white pollution and conform to the concept of green chemistry, so B is not selected;
C, using concentrated sulfuric acid and copper to prepare copper sulfate, the harmful gas sulfur dioxide produced in the reaction process pollutes the atmosphere, which does not conform to the concept of green chemistry, so C is selected;
D, the atomic utilization rate of this reaction is 100%, and it does not produce pollutants, which conforms to the concept of green chemistry, so D is not selected;
So choose C.