1.1 A brief history of the development of carbon fiber and graphite fiber
1.1.1 Pioneers in the development of carbon fiber-Swan and Edison
1.1.2 Polyacrylonitrile Inventor of PAN-based carbon fiber - Akio Shindo
1.1.3 The importance of raw silk from the development history of Toray's carbon fiber
1.1.4 The process of developing PAN-based carbon fiber in my country
1.2 The current major manufacturers and product properties of PAN-based carbon fiber in the world
1.2.1 Small tow PAN-based carbon fiber
1.2.2 Large tow carbon fiber
1.3 Development Trend of Carbon Fiber
1.4 Application Fields
References 2.1 Crystalline State and Multiple Structures of Polyacrylonitrile
2.1. 1 The unit cell and conformation of polyacrylonitrile
2.1.2 The spherulite and its multiple structures of polyacrylonitrile
2.1.3 The configuration of polyacrylonitrile
2.2 Polymerization
2.2.1 Principle of homogeneous solution free radical polymerization
2.2.2 Molecular weight regulator
2.2.3 ***Polymer monomer and its reactivity rate
2.2.4 Polymerization method
2.2.5 Ammoniation
2.2.6 Batch mixing and mixing
2.2.7 Stripping and degassing
2.3 Spinning
2.3.1 Phase separation during solidification and fiber formation
2.3.2 Phase separation during solidification Double diffusion
2.3.3 Wet spinning
2.3.4 Dry jet wet spinning
2.3.5 Spinneret
2.3.6 Drafting and orientation
2.3.7 Drying and densification
2.3.8 Relaxation and heat setting
2.3.9 Ceramic guide wire and its guide roller
2.3.1 Positioning groove roller for 0 spinning
2.4 Analysis, testing and characterization (polymerization? spinning? raw yarn)
2.4.1 Use nuclear magnetic resonance to determine the composition and stereoregularity of polymers
2.4.2 Use infrared spectroscopy to determine the composition of polymers
2.4.3 Characteristics Determination method of viscosity [η] and its relationship with weight average molecular weight (Mw)
2.4.4 Determination of number average molecular weight (Mn) and molecular weight distribution of polymers by osmotic pressure method
2.4.5 Determination of molecular weight and molecular weight distribution by gel permeation chromatography (GPC)
2.4.6 Determination method of conversion rate
2.4.7 Determination method of critical concentration
2.4.8 Determination method of wettability between spinning solution and coagulation solution
2.4.9 Determination method of spinning solution viscosity spot (viscosity CV value)
2.4.10 Use TEM to observe the diameter of fibril - the source of fine crystallization
2.4.11 Determination method of tensile modulus of solidified filament and fineness of solidified filament
2.4.12 Use mercury porosimetry to determine the porosity and average pore size of the solidified wire strips
2.4.13 Use DSC method to determine the pore size of the solidified wire strips
2.4.14 Determination of the porosity of raw silk by density method
2.4.15 Determination of the number of micropores in solidified silk strips by small-angle X-ray scattering
2.4.16 Phase separation and swelling Degree and its determination method
2.4.17 Determination method of residual solvent content in silk thread after washing
2.4.18 Determination of boron (B) in raw silk thread using secondary ion mass spectrometer Radial distribution
2.4.19 Determination of crystallographic orientation of PAN protofilaments by WAXD
2.4.20 Method for determination of crystallinity and crystallite size of PAN protofilaments
2.4
.21 Use the density method to calculate the density of the amorphous region
2.4.22 Use the Determination of the total orientation of cyano groups by color method
2.4.24 Determination of the orientation degree of the amorphous region of PAN protofilaments by dye dichroism method
2.4.25 Determination of the total orientation of fibers by sound velocity method
2.4.26 Glass transition temperature and its determination method
2.4.27 Determination method of fiber density and relative density
2.4.28 Densification of PAN raw filaments Determination method of properties
2.4.29 Devouring degree and test method
2.4.30 Determination method of fineness and its CV value
2.4.31 Boiling water shrinkage Determination
2.4.32 Determination of fiber moisture content
2.4.33 Determination of single filament diameter and its CV value
2.4.34 Single filament morphology
2.4.35 Glossiness of fiber and its measurement method
2.4.36 Determination of surface roughness coefficient of wet-spun PAN precursor using scanning electron microscope
2.4. 37 Evaluation of maximum draw rate device for PAN precursor
Reference 3.1 Changes during pre-oxidation process
3.1.1 Physical changes
3.1.2 Chemistry Reaction
3.1.3 Structural transformation
3.2 Pre-oxidation mechanism
3.2.1 Structural transformation and color change
3.2.2 Pre-oxidation Main reactions during the oxidation process
3.3 Physical property changes during the pre-oxidation process
3.3.1 Drawing and shrinkage
3.3.2 Temperature and temperature gradient
3.3.3 Decline in fiber strength
3.3.4 Change in density
3.4 One of the quality control indicators in the pre-oxidation process (radial distribution of oxygen and homogeneous pre-oxidation wire)
3.5 Pre-oxidation equipment and its process parameters
3.5.1 Overview
3.5.2 Pre-oxidation furnace
3.6 Head-to-tail connection technology
3.7 Quality inspection of pre-oxygenated wire and related measurement methods
3.7.1 Determination method of oxygen content in pre-oxygenated wire
p>3.7.2 Method for determination of moisture content (moisture content) of pre-oxidized yarn
3.7.3 Method for determination of relative density and density of pre-oxidized yarn
3.7. 4 Use XRD to determine the aromatization index
3.7.5 Use infrared spectroscopy to determine the relative degree of cyclization
3.7.6 Use infrared spectroscopy to determine the residual cyano group in the pre-oxidized silk
p>3.7.7 Determination of cyclization degree (aromatization index) by DSC
3.7.8 Determination method of skin-core structure
3.7.9 Formic acid solubility
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3.7.10 Use secondary ion mass spectrometer to determine the radial distribution of O, Si, and B in the fiber
3.7.11 Determination method of limiting oxygen index
3.7 .12 Determination method of runaway oxidation temperature
3.7.13 Determination method of flame shrinkage retention rate
3.7.14 Determination method of moisture in pre-oxidation furnace
References 4.1 Solid phase carbonization mechanism
4.1.1 Polyacrylonitrile carbonization mechanism
4.1.2 Main reactions of solid phase carbonization
4.2 Porosity generation rules and Its impact on the properties of carbon fiber
4.2.1 The changing pattern of pores and its impact on the tensile strength of carbon fiber
4.2.2 Density and porosity
4.2.3 Effect of pore size and shape on carbon fiber tensile strength
4.3 Structural evolution during carbonization
4.3.1 Sheath and core
Structure
4.3.2 Changes in structural parameters
4.4 Low-temperature carbonization process and equipment
4.4.1 Overview of carbonization
4.4.2 Low-temperature carbonization equipment
4.4.3 Non-contact labyrinth seal device
4.4.4 Tar generation and removal method
4.4.5 Waste gas treatment
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4.4.6 Sealing nitrogen and carrier gas nitrogen
4.4.7 Drafting unit and grooved roller
4.5 High temperature carbonization furnace
4.5. 1 Heating element of high-temperature carbonization furnace
4.5.2 Several other technical elements for designing high-temperature carbonization furnace
4.5.3 Types of high-temperature carbonization furnace
4.5 .4 Drafting
4.5.5 Positioning groove roller
4.6 Determination method of carbon fiber
4.6.1 Ultrasonic pulse method to measure the modulus of carbon fiber online
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4.6.2 Use fluorescence X-ray method to determine the silicon content of carbon fiber
4.6.3 Use laser Raman spectroscopy to determine the radial distribution of carbon fiber crystallinity
4.6. 4 Use electron spin resonance (ESR) to study the structural characteristics of carbon fiber
4.6.5 Use electron energy loss spectroscopy to determine the radial distribution of nitrogen
4.6.6 Online determination Tow width methods and devices
4.6.7 Internal pressure measurement method of high-temperature carbonization furnace
References 5.1 Graphitization mechanism
5.1.1 Solid phase Graphitization
5.1.2 Shape factor of graphite crystallites
5.1.3 Graphitization sensitive temperature
5.1.4 Relationship between layer spacing d002 and HTT and Its (002) lattice image
5.1.5 Use HRSEM to observe the structure and morphology of graphite fiber
5.2 Catalytic graphitization
5.2.1 Catalytic graphitization and its effect
5.2.2 Boron and its catalytic graphitization
5.2.3 Introduction of boron
5.3 Graphitization furnace and types
5.3.1 Tam type resistance furnace
5.3.2 Induction graphitization furnace
5.3.3 Radio frequency graphitization furnace
5.3.4 Plasma Volume graphitization furnace
5.3.5 Light energy graphitization furnace
5.4 Graphitization degree and its evaluation method
5.4.1 Graphitization degree
5.4.2 Magnetoresistance
5.4.3 Sheath-core structure of graphite fiber
Reference 6.1 Interface transfer efficiency
6.1.1 Wetting and contact angle
6.1.2 Surface treatment and surface energy
6.2 Interface of composite materials
6.2.1 Principle of generation of interface layer
6.2.2 Mechanical fitting (anchoring effect)
6.2.3 Chemical bonding
6.3 One of the surface treatment methods of carbon fiber - anodization
6.3.1 Principle of anodic electrolytic oxidation method
6.3.2 Continuous direct energization anodizing device
6.3.3 Pulse energization anodizing device
6.3.4 Non-contact energized anodic electrolytic oxidation device
6.3.5 Main process parameters of anodizing
6.4 Ozone surface treatment method
6.4.1 Ozone and its main properties
6.4.2 Ozone surface treatment method
6.5 Evaluation method of surface treatment effect
6.5.1 Test of interlaminar shear strength Method
6.5.2 Test method for interface shear strength
Reference 7.1 Sizing agent
7
.1.1 Sizing agent and its interface properties
7.1.2 Function and requirements of sizing agent
7.2 Composition of sizing agent
7.2.1 Main sizing agent for carbon fiber Agent - bisphenol A epoxy resin
7.2.2 Modification of bisphenol A epoxy resin
7.2.3 Sizing auxiliary agent
7.3 Emulsion Preparation method of type sizing agent - phase transfer method
7.4 Sizing method of carbon fiber
7.4.1 Expansion mechanism of sizing device
7.4.2 With Sizing device in air flow field
7.4.3 Sizing device with air blowing slit
7.4.4 Sizing device with circulation system
7.5 Several types Preparation of sizing agent
7.5.1 Combined functional sizing agent
7.5.2 Emulsifying sizing agent
7.5.3 Nano-modified sizing agent
7.5.4 Oil-soluble sizing agent
7.5.5 Toughened modified sizing agent
7.6 Performance indicators of sizing and its evaluation method
7.6.1 Fiber opening evaluation device
7.6.2 Method for measuring the particle size of emulsion-type sizing agents
7.6.3 Method for measuring the aging stability of sizing agents
7.6.4 Determination method of sizing amount
7.6.5 Determination method of hair number
7.6.6 Determination method of friction coefficient
7.6.7 Evaluation method of wettability
7.6.8 Drape value D and its determination method
7.6.9 Moisture content and equilibrium moisture content
7.6.1 0 Use the Wilhelmy hanging plate method to determine the sizing properties
References 8.1 Abundance and properties of carbon
8.2 Hybrid orbitals and bonding principles of carbon atoms
8.2.1 SP3 hybridization
8.2.2 SP2 hybridization
8.2.3 SP hybridization
8.3 Crystal structure of carbon
8.3.1 Diamond
8.3.2 Graphite
8.3.3 Carbene
8.4 Phase diagram of carbon and sublimation of carbon
8.4.1 Phase diagram of carbon
8.4.2 Sublimation of carbon
8.5 Various forms and structures of carbon
8.6 Structure of carbon fiber
p>8.6.1 Sheath-core structure of carbon fiber
8.6.2 Pore structure of carbon fiber
8.6.3 Structural model of carbon fiber
8.7 Test Methods
8.7.1 Use XRD to determine the structural parameters of carbon fibers
8.7.2 Use electron microscopy to study the structure of carbon fibers
8.7.3 Use XRD to determine the degree of orientation
8.7.4 Use ESR to study the fine structure of carbon fiber
8.7.5 Use Raman spectroscopy to study the heterogeneity of carbon fiber structure
8.8 Morphology of carbon fiber and graphite fiber Structure and properties
8.8.1 Curvature of tassel-like fibrils
8.8.2 Structural parameters and properties of carbon fibers
8.8.3 Non-linear properties of carbon fiber structures Homogeneity
8.8.4 High-strength and high-model carbon fiber (MJ series)
Reference 9.1 Tensile strength and defects
9.1.1 Graffis Micro Crack theory
9.1.2 Types of defects
9.1.3 Dispersion of carbon fiber tensile strength and its characterization method
9.2 Compressive strength of carbon fiber and graphite fiber
9.2.1 Compressive strength
9.2.2 Compressive strength of carbon fiber composite materials
9.2.3
Method for determining compressive strength
9.3 Tensile modulus
9.4 Thermal properties
9.4.1 Thermal expansion
9.4.2 Thermal conductivity Rate
9.4.3 Heat capacity
9.4.4 Thermal properties of composite materials
9.4.5 Thermal oxidation
9.5 Electricity of carbon fiber Performance
9.5.1 Principle of conductivity
9.5.2 Resistivity of carbon fiber and its influencing factors
9.5.3 Method for measuring resistivity of carbon fiber
9.6 Magnetic properties
9.6.1 Magnetic resistance
9.6.2 Magnetic susceptibility
References 10.1 Carbon fiber reinforced resin matrix composites
10.1.1 Thermosetting matrix resin
10.1.2 Molding technology
10.1.3 Preformed intermediate
10.1.4 Thermoplastic matrix resin
10.2 Carbon/Carbon Composite Materials
10.2.1 Manufacturing of Carbon/Carbon Composite Materials
10.2.2 Manufacturing of C/C Composite Materials from Chopped Carbon Fibers
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10.2.3 Anti-oxidation treatment
10.3 Carbon fiber reinforced ceramic composites
10.3.1 Carbon fiber reinforced silicon carbide (CFRSiC) composites
10.3.2 Carbon fiber reinforced silicon nitride composites
10.4 Carbon fiber reinforced metal matrix composites
10.4.1 Two-phase interface layer
10.4.2 Carbon fiber surface Protection methods
10.4.3 Carbon fiber reinforced aluminum matrix composite materials (CF/Al)
10.4.4 Carbon fiber reinforced copper matrix composite materials (CF/Cu)
10.5 Carbon fiber paper and carbon fiber cloth
10.5.1 Pretreatment of carbon fiber for papermaking
10.5.2 Manufacturing process of high-grade carbon fiber paper
10.5.3 Carbon fiber cloth
10.6 Carbon fiber reinforced rubber material
10.6.1 Selection of carbon fiber
10.6.2 RFL emulsion
References 11.1 in Applications in aerospace and military industry
11.1.1 Space shuttle
11.1.2 Space probe
11.1.3 Artificial satellite
11.1.4 Rockets and missiles
11.1.5 Ship applications
11.1.6 Graphite bombs
11.1.7 Enriched uranium and atomic bombs
11.2 Applications in the aviation and military fields
11.2.1 Fighters
11.2.2 Helicopters
11.2.3 Unmanned aircraft
p>11.2.4 Civil airliners and large aircraft
11.2.5 Braking materials
11.2.6 Stealth materials and stealth fighters
Reference Literature 12.1 Application in the automobile industry
12.1.1 Lightweight automobiles, energy saving and consumption reduction
12.1.2 Compressed gas tanks (bottles)
12.2 Carbon fiber Composite material roller
12.3 Application in the field of new energy
12.3.1 Wind power generation
12.3.2 Solar power generation
12.3.3 Carbon fiber composite core cable
12.3.4 Application in offshore oil fields
12.3.5 Application in nuclear energy
12.4 In infrastructure and civil construction Applications
12.4.1 Matching of application form and performance
12.4.
2 Carbon fiber composite rope
12.5 Electric heating, antistatic and heat-resistant products
12.5.1 Electric heating products
12.5.2 Antistatic products
12.5.3 Heat-resistant products
12.6 Sports and leisure equipment
12.7 Application of carbon fiber in medical devices, biomaterials and medical equipment
12.7. 1 Medical equipment
12.7.2 Biomaterials
12.7.3 Medical equipment
12.8 Carbon fiber repairs aquatic ecological environment
12.9 Other aspects Applications
12.9.1 Rail vehicles
12.9.2 Robot components
12.9.3 Laptops
12.9.4 Universe Components of telescopes
12.9.5 Packing and sealing rings
12.9.6 Audio equipment and musical instruments
References