MSDS is a comprehensive legal document on chemical characteristics provided to customers by chemical production or sales enterprises according to legal requirements. Sixteen contents including physical and chemical parameters, explosive performance, health hazards, safe use and storage, leakage disposal, first aid measures and relevant laws and regulations are stipulated.
MSDS briefly describes the harm of chemicals to human health and environment, and provides information on how to handle, store and use chemicals safely. As a service provided to users, production enterprises should provide users with safety instructions along with chemical commodities, so that users can understand the related hazards of chemicals and take the initiative to protect them when using them, thus reducing occupational hazards and preventing chemical accidents. At present, the United States, Japan, the European Union and other developed countries have generally established and implemented the MSDS system, requiring manufacturers of dangerous chemicals to provide product safety instructions when selling, transporting or exporting products.
In all countries of the world, whether it is domestic trade or international trade, the seller must provide legal documents describing the products. Because the legal documents of chemicals management and trade are different in different countries, even in different states of the United States, and some of them change every month, if the MSDS provided is incorrect or the information is incomplete, they will be investigated for legal responsibility. Therefore, the quality of MSDS is an important symbol to measure a company's strength, image and management level.
Ningbo Dumei Certification Service Co., Ltd. is called Dumei for short. Provide product MSDS service, and the relevant contact information can be found on the website in the extended reading at the bottom of the article.
procedure
1. Fill in the MSDS Application Form and send it back to Ningbo Mei Duo Testing Co., Ltd.-Room 804, Building 3, Wante Business Center, Jiangdong High-tech Zone, Ningbo.
2. After receiving the application form, the relevant personnel of Ningbo Mei Duo Testing Co., Ltd. will contact the customer by phone and send a payment notice. The customer must send the bank voucher back to Ningbo Mei Duo Testing Co., Ltd. and arrange the preparation of MSDS after receiving the memorandum.
3. After 3.MSDS is completed, the relevant laboratory personnel will fax the report to your company first, and then handle it according to the method selected by the customer on the application form.
1. MSDS meeting the requirements of OSHA in the United States shall include the following contents.
Item 1: Manufacturer and contact information
Item 2: Composition of Hazardous Chemicals
Item 3: Physical and chemical characteristics
Item 4: Combustion and explosion data
Item 5: reactivity data
Item 6: Health Hazard Data
Item 7: Safe operation and use
Item 8: Protection methods
2. MSDS meeting the requirements of WHMIS in Canada shall include the following contents.
Item 1: product name and manufacturer information
Item 2: Composition of Hazardous Chemicals
Item 3: Physical characteristics
Item 4: Fire fighting or explosion data
Item 5: reactivity data
Item 6: Toxicological characteristics
Item 7: Preventive measures
Item 8: First aid methods
Item 9: Preparation of information
3. MSDS content recommended by American Standards Institute ANSI and International Standards Organization ISO.
Item 1: chemical name and manufacturer information
Item 2: Chemical Composition Information
Item 3: Hazard information
Item 4: First aid measures
Item 5: Fire Prevention Measures
Item 6: Emergency treatment of leakage
Item 7: Operation and storage
Item 8: Contact control and personal protective measures
Item 9: Physical and chemical characteristics
Project 10: stability and reactivity
Project 1 1: toxicological information
Project 12: Ecological Information
Item 13: Abandoned disposal
Project 14: Transportation Information
Project 15: Regulatory Information
Project 16: Other information
In order to meet the international standard EQV ISO11014-11994 (e), China has also formulated the relevant standard GB 16483-2000 "Provisions for the Compilation of Chemical Safety Technical Specifications".
It is stipulated that msds should have sixteen parts.
1 chemical products and company logo
Mainly indicate the chemical name, manufacturer's name, address, postcode, telephone number, emergency telephone number, fax number and email address.
2 composition/composition information
Indicate whether the chemical is pure or a mixture. For pure chemicals, the chemical name or trade name and common name should be given. Mixture, should give the concentration or concentration range of harmful components. Whether it is a pure chemical substance or a mixture, if it contains harmful components, the CAS number should be given.
3 Hazard Summary (haxards Summary)
This paper briefly summarizes the main hazards and impacts of this chemical, including: hazard types, invasion routes, health hazards, environmental hazards, explosion hazards and other information.
4. First aid measures.
Refers to the brief treatment methods of self-help or mutual rescue on the spot when the operator is accidentally injured, including eye contact, skin contact, inhalation and accidental eating.
5 fire control measures
Mainly refers to the special physical and chemical risks of chemicals, suitable fire extinguishing media, inappropriate fire extinguishing media and personal protection of firefighters, including:
Hazard characteristics, fire extinguishing media and methods, fire extinguishing precautions, etc.
6 Emergency measures for leakage (accidental release measures)
Refers to the simple and effective emergency measures, precautions and elimination methods that can be taken on site after chemical leakage, including emergency actions, emergency personnel protection, environmental protection measures and elimination methods.
7 Handling and storage.
Mainly refers to the information of chemical operation, disposal and safe storage, including: safety precautions, safe storage conditions and precautions in operation and disposal.
8 Contact Control/Personal Protection (Contact Control/Personal Protection)
In the process of production, operation, disposal, handling and use of chemicals, protective methods and means are adopted to protect workers from chemical hazards. Including:
Maximum allowable concentration, engineering control, respiratory protection, eye protection, body protection, hand protection and other protection requirements.
9 Physical and chemical properties.
Mainly describe the appearance and physical and chemical properties of chemicals, including:
Appearance and properties, ph value, boiling point, melting point, relative density (water = 1), relative vapor density (air = 1), saturated vapor pressure, heat of combustion, critical temperature, critical pressure, octanol/water partition coefficient, flash point, ignition temperature, explosion limit, solubility, main uses and other special physical and chemical properties.
Stability and reactivity of 10
This paper mainly describes the information about the stability and reactivity of chemicals, including stability, banned compounds, conditions to avoid contact, polymerization hazards and decomposition products.
1 1 toxicological information
Provide toxicological information of chemicals, including acute toxicity (LD50, LD50), irritation, sensitization, subacute and chronic toxicity, mutagenicity, teratogenicity, carcinogenicity, etc.
12 ecological information
This paper mainly expounds the environmental ecological effects, behaviors and fate of chemicals, including biological effects (such as LD50, LD50), biodegradability, biological enrichment, environmental migration and other harmful environmental impacts.
13 disposal
Refers to the safe disposal methods of packaging contaminated by chemicals and chemicals with no use value, including disposal methods and precautions.
14 transport information (transport information)
Mainly refers to the classification number of domestic and foreign chemical packaging and transportation requirements and transportation regulations, including: dangerous goods number, packaging category, packaging mark, packaging method, UN number and transportation precautions.
15 regulatory information
Mainly the legal provisions and standards of chemical management.
16 Other information
It mainly provides other information of great significance to safety, including references, reporting time, reporting department and data auditing unit.
Guide for filling in chemical safety technical specifications
A 1 chemical products and company logo
A 1. 1 Fill in the scientific name, common name or product name of the chemical in Chinese [A].
A 1.2 fill in the scientific name, common name or product name of the chemical substance in English [A].
A 1.3 name of production enterprise: fill in the full name of chemical production enterprise in Chinese and English [A].
A 1.4 address fill in the detailed address of the chemical production enterprise [A].
A 1.5 postal code: fill in the postal code of the chemical production enterprise [A].
A 1.6 fax number fill in the fax number of the chemical production enterprise [A].
A 1.7 enterprise emergency telephone number [A] of chemical production enterprise to be dialed in case of emergency.
A 1.8 email address fill in the email address of chemical production enterprise [C].
A 1.9 technical specification code fill in the product safety technical specification code [A].
A 1. 10 Effective Date Fill in the date of preparation or revision of this safety technical specification [A].
A 1. 1 1 National Emergency Telephone Fill in the national chemical accident emergency telephone number and fire emergency telephone number dialed in case of emergency [A].
A2 composition/composition information.
A2. 1 main components
A) Fill in the main harmful components of the mixture and their content or content range.
B) Fill in the name and concentration range of harmful components for pure products.
A2.2 CAS number: fill in the chemical abstracts index registration number of harmful components in chemicals.
A3 Hazard Summary (Hazard Summary)
A3. 1 Hazard category shall be filled in according to GB 13690-92 Classification and Labeling of Common Hazardous Chemicals.
A3.2 Invasion route: the route through which chemicals invade the human body and cause harm, such as inhalation, ingestion and skin contact.
A3.3 Health hazards Fill in the typical clinical manifestations of toxic poisoning, including symptoms and manifestations of main target organs, acute poisoning and chronic poisoning, and carcinogenicity.
A3.4 Environmental Harm Briefly describe the harm caused by chemicals to various organisms at a certain concentration and the degree of harm caused.
A3.5 Flames and explosions briefly outline the possible hazards caused by chemicals exposed to open flames, high temperatures or oxidants in the air.
A4 first aid measures
Refers to the brief treatment methods that field workers need to take when they are accidentally injured by chemicals. A4. 1 skin contact
A) Take off the violent drugs immediately and clean them with the recommended cleaning medium. See a doctor.
B) Take off the clothes with medium drugs and rinse them with recommended cleaning medium. See a doctor.
C) Take off the contaminated clothes from the harmful products and rinse the skin with the recommended medium.
D) Corrosive products should be cleaned with recommended media. If you burn, see a doctor.
A4.2 Eye contact
A) Lift the eyelids immediately with severe drugs, and rinse eyes with plenty of water for at least 15 minutes. See a doctor.
B) For moderate drugs, immediately lift the eyelids and rinse eyes with plenty of water for at least 15 minutes. See a doctor.
C) Lift the eyelids containing harmful substances and rinse the eyes with plenty of water.
D) Immediately lift corrosive products to eyelids, rinse them with running water or normal saline, and treat them by doctors.
A4.3 inhalation
A) Severe drugs, moderate drugs and harmful substances should be quickly evacuated from the site to fresh air; If breathing stops, give artificial respiration; If breathing is difficult, give oxygen (take it immediately if there is a suitable antidote).
B) The corrosive products shall be immediately moved to a place with fresh air, and artificial respiration shall be carried out if necessary. See a doctor.
A4.4 intake
A) Seek medical treatment immediately.
B) For moderate drugs, seek medical attention immediately.
C) Hazardous products shall be disposed of immediately.
D) For corrosive products, seek medical attention immediately.
A5 fire protection measures
A5. 1 Hazard characteristics mainly include possible hazards when exposed to open flames, high temperatures and oxidants, reactivity, oxidation and corrosiveness when exposed to water, acid, alkali and some active substances.
A5.2 harmful combustion products fill in the products after combustion, such as harmful gases.
A5.3 Fire extinguishing method Fill in the fire extinguishing method and extinguishing agent. For different types of chemicals, appropriate fire extinguishing media should be selected according to their performance and state.
A5.4 Fire precautions and measures
A) Fill in the protective clothing that firefighters should choose for individual protection, such as full-body fire suit, fire suit, fire boots, positive pressure self-contained breathing apparatus, etc.
B) Fill in the fire extinguishing agent that should be banned, such as water, carbon dioxide, dry powder, foam, sand, etc.
A6 leakage emergency measures (accidental release measures)
A6. 1 Emergency can be filled in with reference to the following levels:
A) Call the police quickly, evacuate relevant personnel and isolate the polluted area; The number of evacuees and the size of the isolated contaminated area depend on the amount of leakage and the toxicity of the leakage.
B) cut off the power supply. For flammable and explosive leakage, the fire source must be cut off before removal.
C) As an emergency, emergency personnel should do a good job in leakage protection, and the protection requirements are strict.
D) Precautions: Some substances can't be directly contacted, some substances can be sprayed with water mist to reduce volatilization, some substances can't be sprayed with water, and some substances need to be cooled and shockproof, so they should be selected according to specific substances and leakage parts.
E) Elimination methods Specific elimination methods are given according to the physical state (gas, liquid and solid), danger (explosive characteristics and toxicity) and environmental protection requirements of chemicals.
F) Equipment: the name of the equipment and equipment needed for emergency treatment.
A7 Handling and storage
A7. 1 Operation precautions refer to safety precautions and personal protection during chemical operation.
A7.2 Storage precautions should be filled in with reference to the following levels. Basic conditions and requirements for storage? Storage restrictions? Precautions? Prohibited compounds? Fire and explosion protection requirements? Precautions for repackaging.
A8 exposure control/personal protection.
A8. 1 The maximum allowable concentration shall be filled in according to the national hygiene standards. If there is no national standard, you can refer to the relevant foreign standards, expressed by (mg/m3).
A8.2 Monitoring method Fill in the monitoring method of harmful substances in the air of the workshop.
A8.3 Engineering control mainly fills in the protection and isolation measures such as sealing and ventilation in the production process, and does not refer to the automatic control of industrial production process.
A8.4 Protective articles for respiratory system To prevent harmful substances from entering the human body from the respiratory system, the following three factors should be considered, namely, the working environment, the harm degree of poisons entering the human body from the respiratory system and the protective ability of protective articles. Air respirator, self-contained respirator, oxygen respirator, filter gas mask (semi-full face mask) and dust mask are recommended.
A8.5 Eye protection A mask that protects the eyes from poison. Safety masks, safety glasses, chemical safety glasses, safety goggles and safety masks are mainly recommended.
A8.6 Physical protection against skin damage. According to the toxicity and contact concentration of poisons, choose mask-type adhesive tape anti-virus clothing, integrated adhesive tape anti-virus clothing, rubber work clothes, anti-virus penetration work clothes, breathable anti-virus clothing and general work anti-virus clothing.
A8.7 Hand protection mainly includes protective gloves, rubber gloves, latex gloves, acid alkali resistant gloves, chemical-resistant gloves and skin protective film.
A8.8 Other protection mainly includes personal hygiene requirements of operators, on-site preventive measures, poison monitoring and routine experience [C].
Physical and chemical properties of A9.
A9. 1 The appearance and properties of the product are mainly the color, smell and existing state of the substance at normal temperature and pressure [A].
A9.2 PH value Fill in the PH value.
A9.3 Fill in the numerical value of melting point under normal temperature and pressure, and the numerical value under special circumstances shall indicate the technical conditions.
A9.4 Boiling point Fill in the boiling point value under normal temperature and pressure, and the value obtained under special conditions shall indicate the technical conditions. Before boiling, the sublimation value or decomposition value should be stated, and the technical conditions should be marked.
A9.5 Relative density (water = 1) Fill in the ratio of the density of a substance at 20℃ to that of water at 4℃.
A9.6 Relative steam density (air = 1) Fill in the ratio of steam density to air density at 0℃.
A9.7 Saturated vapor pressure at a certain temperature, the pressure when pure liquid and vapor reach equilibrium in a vacuum container, in kPa, indicating the temperature [c].
A9.8 Heat of combustion 1 heat generated when a molar substance is completely burned, in (kJ/mol) [C].
A9.9 Critical temperature (℃) The maximum allowable temperature when a gas or liquid is pressurized is expressed as (℃) [C].
A9. 10 Critical pressure The minimum pressure required for gas and liquid at critical temperature, expressed in MPa [C].
A9. 1 1 octanol/water partition coefficient is an important parameter, which can be used to predict the adsorption, biological absorption, octyl storage and biological enrichment of a chemical in soil. When chemicals are dissolved in octanol/water mixture, the concentration ratio of chemicals in octanol and water is called distribution coefficient, which is usually expressed in logarithmic form with 10 as the base.
A9. 12 Flash Point Under specified conditions, heat the sample to the lowest temperature at which the flash point can occur when the mixture of steam and air contacts the flame, and indicate the open or closed cup value when filling.
A9. 13 Ignition temperature (spontaneous combustion temperature) refers to the lowest temperature of the reaction vessel wall when the mixture of combustible gas and air in the vessel is heated at normal temperature and pressure.
A9. 14 Upper explosive limit The upper explosive limit of combustible gas mixture formed by mixing combustible gas with air, with gas-liquid unit as (%V/V) and dust as (mg/m3).
A9. 15 Lower explosive limit The lower explosive limit value of combustible gas mixed with air is expressed in the same unit as the upper explosive limit value.
A9. 16 Solubility The solubility of a substance in a solvent at room temperature and pressure is expressed as miscible, soluble, soluble, slightly soluble and insoluble respectively.
A9. 17 main uses Fill in its main uses [C].
A9. 18 Other physical and chemical properties Set non-fixed data items for specific properties of certain substances, such as particle size, volatile organic content, evaporation rate, viscosity, radioactivity, freezing point, corrosiveness, explosion point, explosion speed, minimum ignition energy, etc. C。
Stability and reactivity of A 10
A 10. 1 Whether the chemical behavior of a substance is stable under normal temperature and pressure or under expected storage conditions is expressed by stability and instability respectively.
A 10.2 conditions to avoid contact indicate external conditions that may lead to harmful effects of chemicals, such as heat, light, contact with air and moisture, vibration and extrusion.
A 10.3 prohibited compounds clearly indicate substances with contradictory chemical properties.
A 10.4 polymerization risk indicates whether unexpected polymerization reaction can occur under external conditions, which is expressed by energy occurrence and non-occurrence respectively.
The decomposition products of A 10.5 qualitatively indicate the final harmful substances that may be produced when substances are burned or undergo chemical reactions.
A 1 1 toxicological information
Acute toxicity A 1 1. 1 Acute toxicity is expressed by LD50 and LC50.
A 1 1.2 subacute and chronic toxicity mainly includes the toxic manifestations and histopathological examination results of animals after subacute and chronic exposure [C].
A 1 1.3 Irritability Fill in the experimental results of animal eye and skin irritation. The intensity of stimulation is expressed as mild, moderate and severe respectively.
A 1 1.4 Allergy fill in the experimental results after animal poisoning [C].
A 1 1.5 mutagenicity. Fill in the data of salmonella recovery test (Ames test) and other test results. With the lowest dose said [C].
A 1 1.6 teratogenicity Fill in whether the chemical is teratogenic. It can be expressed by the lowest dose [C].
A 1 1.7 Carcinogenicity Fill in the evaluation conclusion of the expert group of the International Centre for Research on Cancer (IARC). It can be expressed by the lowest dose [C].
A 1 1.8 other fill in other relevant data, such as reproductive toxicity and neurotoxicity [C].
A 12 ecological information
The ecotoxicity of A 12. 1 shows that the toxicity of the chemical to aquatic organisms (algae, invertebrates and fish), terrestrial organisms (plants, locusts and birds) and beneficial microorganisms can be divided into 50 lethal doses (LD50), 50 lethal concentrations (LC50), no-effect doses (NOEL) and 50 tolerant doses.
A 12.2 biodegradability indicates whether the chemical is biodegradable, and its biodegradability is explained by experimental data and expressed as the percentage of biodegradation within a period of time.
A 12.3 Non-biodegradable means whether the chemical is non-biodegradable, such as photolysis and hydrolysis.
A 12.4 bioaccumulation and bioaccumulation indicate whether the chemical has bioaccumulation characteristics. It can be divided into biological enrichment in aquatic and terrestrial environments. After chemicals are ingested by organisms and kept for a period of time, when the four interrelated processes of ingestion, distribution, transformation and excretion form a dynamic balance, the concentration ratio of chemicals in biological and environmental media is constant. For example, fill in the BCF value of fish [C].
A 12.5 other harmful effects refer to the potential effects on ozone layer destruction and global warming [C].
A 13 abandoned disposal
A 13. 1 The nature of the waste indicates whether the waste belongs to hazardous waste. The standard is the national hazardous waste list.
A 13.2 waste disposal methods only fill in the final disposal methods of hazardous chemicals that cannot be reused, such as incineration, chemical oxidation, dissolution, deep burial, etc.
A 13.3 preventive measures for waste conditions needed to protect operators and environment when waste chemicals and their outer packaging are used.
A 14 transport information
A 14. 1 quantity of dangerous goods, fill in the danger category and classification number according to GB6944-86.
A 14.2 UNNo。 Quantity specified in the United Nations Recommendations on the Transport of Dangerous Goods.
A 14.3 The degree of danger of dangerous goods shall be filled in the packaging mark, and the danger (Grade I and II) shall be clearly indicated.
A 14.4 the packaging category is determined according to the classification principle of GB/T 15098-94.
A 14.5 The packing method shall be filled in according to the Management Rules for the Transport of Dangerous Goods (promulgated by the Ministry of Railways) and the United Nations proposal on the transport of dangerous goods.
A 14.6 transportation precautions: when filling in the chemical transportation, you should pay attention to the transportation conditions, preventive measures, packaging methods, materials, signs, etc. At the same time, we should pay attention to prevent possible accidents (shipping, sea transportation, railway transportation, road transportation, etc.). ).
A 15 regulatory information
A 15. 1 Domestic chemical safety laws and regulations mainly provide information on domestic chemical laws and regulations for chemical managers, users and operators. For example, Regulations on Safety Management of Hazardous Chemicals [A].
A 15.2 international laws and regulations mainly provide information about international laws and regulations on chemical management and operation [C].
A 16 other information
A 16. 1 references
A 16.2 time for filling in the form [A].
A 16.3 the department fills in the form and the department fills in this CSDS [A].
A 16.4 the data auditing unit shall fill in this CSDS unit [A].
A 16.5 modification notes [A].
A 16.6 other supplementary information materials or explanations [C].