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(1)①Ni is element 28, with 28 electrons outside its nucleus, and the valence electrons at the 3d and 4s levels of Ni atom are its valence electrons. According to the structural principle, the valence electron arrangement formula of Ni atom is 3d84s2, so the answer is 3d84S2;

② The number of hydrogen molecules in the battery is 8× 14+2× 12 = 3, and the number of La atoms is 8× 18 = 1, so the ratio of hydrogen molecules to La atoms in the material is 3: 1, that is to say, it contains/kloc-. The number of H2 adsorbed by La alloy is 0, so the answer is: 3NA;;

(2)① The stronger the nonmetallic nature of an element is, the stronger its electronegativity is, and the nonmetallic nature of O, N, C and H gradually weakens, so the electronegativity of O, N, C and H also gradually weakens. The order of electronegativity of O, N, C and H is O > N > C > H;, so the answer is: O > N > C >.

② There are hydrogen bonds between oxygen atoms and hydrogen atoms in P-nitrophenol hydrate, so the interaction between particles is hydrogen bonds in the process of P-nitrophenol hydrate losing crystal water, so the answer is: hydrogen bonds;

(3) Particles with the same number of atoms and valence electrons belong to isoelectronic bodies, and their structures are similar. Anion and SO42- are isoelectronic bodies, and the outermost electron of each atom in the anion satisfies the 8-electron stable structure, then the ion is NO4 3-, its electron type is:, and the valence electron pair in the ion is 4+ 12 (5+3-4×).