Use the company's network to download movies. Can the company's network supervision department know what you are doing?

It depends on what equipment they use, and some equipment can even be accurate to what software you use and what movies you download.

Even an ordinary enterprise router with behavior management can detect the traffic of your IP, thus inferring whether you downloaded the movie or not.

In short, if your company explicitly prohibits this kind of behavior, it is better not to do it. The IT department must know.